Rice University engineers are using 3-D printers to turn structures that have until now existed primarily in theory into strong, light and durable materials with complex, repeating patterns.
The porous structures called schwarzites are designed with computer algorithms, but Rice researchers found they could send data from the programs to printers and make macroscale, polymer models for testing. Their samples strive to use as little material as possible and still provide strength and compressibility.
The results reported in Advanced Materials are works of art that may someday lead to nanoscale electronic devices, catalysts, molecular sieves and battery components, and on the macroscale could become high-load-bearing, impact-resistant components for buildings, cars, and aircraft.
It may someday be possible, they said, to print an entire building as one schwarzite “brick.”
Schwarzites, named after German scientist Hermann Schwarz, who hypothesized the structures in the 1880s, are mathematical marvels that have inspired a large number of organic and inorganic constructs and materials. The discovery at Rice of the Nobel Prize-winning buckminsterfullerene (or buckyball) provided further inspiration for scientists to explore the design of 3-D forms from 2-D surfaces.
Such structures remained theoretical until 3-D printers provided the first practical way to make them. The Rice lab of materials scientist Pulickel Ajayan, in collaboration with researchers at the University of Campinas, São Paulo, investigated the bottom-up construction of schwarzites through molecular dynamics simulations and then printed those simulations in the shapes of polymer cubes.
“The geometries of these are really complex; everything is curved, the internal surfaces have negative curvature and the morphologies are very interesting,” says Rice postdoctoral researcher Chandra Sekhar Tiwary, who led an earlier study that showed how seashells protect soft bodies from extreme pressure by transferring stress throughout their structures.
From left, Rice University researchers Chandra Sekhar Tiwary, Seyed Mohammad Sajadi, Peter Owuor, Pulickel Ajayan and Robert Vajtai hold samples of 3-D printed schwarzites, porous blocks based on complex mathematical models created in the 19th century and further developed in the 20th. The materials retain their strength at any scale, from the nano to the macro. Image: Jeff Fitlow
“Schwarzite structures are very much the same,” he says. “The theory shows that at the atomic scale, these materials can be very strong. It turns out that making the geometry bigger with polymer gives us a material with a high load-bearing capacity.”
Schwarzites also displayed excellent deformation characteristics, he says. “The way a material breaks is important,” Tiwary says. “You don’t want things to break catastrophically; you want them to break slowly. These structures are beautiful because if you apply force to one side, they deform slowly, layer by layer.
“You can make a whole building out of this material, and if something falls on it, it’s going to collapse slowly, so what’s inside will be protected,” he says.
Because they can take a variety of forms, the Rice team limited its investigation to primitive and gyroid structures, which have periodic minimal surfaces as originally conceived by Schwarz. In tests, both transferred loads across the entire geometry of the structures no matter which side was compressed. That held true in the atom-level simulations as well as for the printed models.
That was unexpected, says Douglas Galvão, a professor at the University of Campinas who studies nanostructures through molecular dynamics simulations. He suggested the project when Tiwary visited the Brazil campus as a research fellow through the American Physical Society and Brazilian Physical Society.
“It is a little surprising that some atomic-scale features are preserved in the printed structures,” Galvão says. “We discussed that it would be nice if we could translate schwarzite atomic models into 3-D printed structures. After some tentatives, it worked quite well. This paper is a good example of an effective theory-experiment collaboration.”
A schwarzite created on a 3-D printer by materials scientists at Rice University makes real a mathematical theory formed more than 100 years ago. The curved surface repeats throughout the structure, which showed excellent strength and deformation characteristics in tests at Rice. Image: Jeff Fitlow
The researchers said their next step will be to refine the surfaces with higher-resolution printers and further minimize the amount of polymer to make the blocks even lighter. In the far future, they envision printing 3-D schwarzites with ceramic and metallic materials on a grander scale.
“There’s no reason these have to be blocks,” says co-author and Rice graduate student Peter Owuor. “We’re basically making perfect crystals that start with a single cell that we can replicate in all directions.”
Rice research assistant Seyed Mohammad Sajadi is lead author of the paper. Co-authors are Rice senior Steven Schara, Associate Research Professor Robert Vajtai and Jun Lou, a professor of materials science and nanoengineering, all of Rice; and postdoctoral researcher Cristiano Woellner and Professor Varlei Rodrigues of the University of Campinas. Ajayan is chair of Rice’s Department of Materials Science and NanoEngineering, the Benjamin M. and Mary Greenwood Anderson Professor in Engineering and a professor of chemistry.
The Air Force Office of Scientific Research and its Multidisciplinary University Research Initiative, the São Paulo Research Foundation, and the Center for Computational Engineering and Sciences at the State University of Campinas supported the research.
Source: Rice University
